Enantioselective Protonation of Radical Anion Intermediates in Photoallylation and Photoreduction Reactions of 3,3-Diaryl-1,1-dicyano-2-methylprop-1-ene with Allyltrimethylsilane

Photoreactions of acetonitrile solutions of 3,3-diaryl-1,1-dicyano-2-methylprop-1-enes (1a–c) with allyltrimethylsilane (2) in the presence of phenanthrene as a photoredox catalyst and acetic acid as a proton source formed photoallylation (3) and photoreduction (4) products via photoinduced electron...

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Detalles Bibliográficos
Autores principales: Maeda, Hajime, Iida, Masayuki, Ogawa, Daisuke, Mizuno, Kazuhiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680834/
https://www.ncbi.nlm.nih.gov/pubmed/31340614
http://dx.doi.org/10.3390/molecules24142677

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680834/
https://www.ncbi.nlm.nih.gov/pubmed/31340614
http://dx.doi.org/10.3390/molecules24142677

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