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Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Complexes Formed by the Self-Assembly of a Hydrophobic Bis(Zn(2+)-cyclen) Complex, Copper, and Barbital Units That Are Functionalized with Amino Acids in a Two-Phase Solvent System

We previously reported on the preparation of supramolecular complexes by the 2:2:2 assembly of a dinuclear Zn(2+)-cyclen (cyclen = 1,4,7,10-tetraazacyclododecane) complex having a 2,2′-bipyridyl linker equipped with 0~2 long alkyl chains (Zn(2)L(1)~Zn(2)L(3)), 5,5-diethylbarbituric acid (Bar) deriva...

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Detalles Bibliográficos
Autores principales: Miyazawa, Yuya, Rahman, Akib Bin, Saga, Yutaka, Imafuku, Hiroki, Hisamatsu, Yosuke, Aoki, Shin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680849/
https://www.ncbi.nlm.nih.gov/pubmed/31277494
http://dx.doi.org/10.3390/mi10070452