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Coinage-Metal Bond between [1.1.1]Propellane and M(2)/MCl/MCH(3) (M = Cu, Ag, and Au): Cooperativity and Substituents
A coinage-metal bond has been predicted and characterized in the complexes of [1.1.1]propellane (P) and M(2)/MCl/MCH(3) (M = Cu, Ag, and Au). The interaction energy varies between −16 and −47 kcal/mol, indicating that the bridgehead carbon atom of P has a good affinity for the coinage atom. The coin...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680963/ https://www.ncbi.nlm.nih.gov/pubmed/31319542 http://dx.doi.org/10.3390/molecules24142601 |