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Reactivity Modes of Cp*M-Type Half-Sandwich Dichalcogenolate Complexes with 2,6-Disubstituted Aryl Azides: The Effects of the Metal Center, Chalcogen, and Ligand Moiety on Product Formation

[Image: see text] Cp*M-type half-sandwich dichalcogenolate complexes bearing either carborane or benzene moieties show diverse reactivity patterns toward two selected 2,6-disubstituted aryl azides under thermal or photolytic conditions. The chalcogen (S and Se) has little effect on the formation of...

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Detalles Bibliográficos
Autores principales: Zhong, Wei, Liu, Xiaoming, Zhu, Hailiang, Zhao, Jing, Yan, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6682133/
https://www.ncbi.nlm.nih.gov/pubmed/31460394
http://dx.doi.org/10.1021/acsomega.9b01364