N-Geminal P/Al Lewis Pair–Alkyne Dipolar Cycloaddition to the Zwitterionic C(2)PNAl-Heterocyclopentene

[Image: see text] The N-geminal P/Al Lewis pair [Ph(2)PN(2,6-iPr(2)C(6)H(3))AlEt(2)](2) (1) has been prepared and studied for reaction with a series of alkynes. The reaction of 1 with RC≡CR yielded zwitterionic C(2)PNAl-heterocyclopentene [Ph(2)(⌜)PN(2,6-iPr(2)C(6)H(3))AlEt(2)](CR=(⌝)CR) (R = Me (2)...

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Detalles Bibliográficos
Autores principales: Ding, Shuang, Li, Jiancheng, Liu, Rui, Fu, Gang, Zhu, Hongping, Liu, Weiping, Ye, Qingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6682165/
https://www.ncbi.nlm.nih.gov/pubmed/31457589
http://dx.doi.org/10.1021/acsomega.7b00236

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6682165/
https://www.ncbi.nlm.nih.gov/pubmed/31457589
http://dx.doi.org/10.1021/acsomega.7b00236

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