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Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives

A regioselective and enantioselective palladium-catalyzed relay Heck alkenylation of alkenylbenzene derivatives to construct remote stereocenters is disclosed. Various β-substituted styrenes were readily obtained in moderate yields with good to excellent levels of enantioselectivity. This strategy p...

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Detalles Bibliográficos
Autores principales: Chen, Zhi-Min, Liu, Jianbo, Guo, Jing-Yao, Loch, Maximillan, DeLuca, Ryan J., Sigman, Matthew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685350/
https://www.ncbi.nlm.nih.gov/pubmed/31588293
http://dx.doi.org/10.1039/c9sc02380a