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The S∴π hemibond and its competition with the S∴S hemibond in the simplest model system: infrared spectroscopy of the [benzene-(H(2)S)(n)](+) (n = 1–4) radical cation clusters

The S∴π hemibond (two-center three-electron, 2c-3e, bond) is an attractive interaction between a sulfur atom and π electrons. The S∴π hemibond is of essential importance in understanding chemistry of sulfur radical cations, and its roles in biochemistry have recently attracted much interest. In the...

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Detalles Bibliográficos
Autores principales: Wang, Dandan, Hattori, Keigo, Fujii, Asuka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685351/
https://www.ncbi.nlm.nih.gov/pubmed/31588295
http://dx.doi.org/10.1039/c9sc02476j