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Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids

The synthesis and catalytic reactivity of a class of water-tolerant cationic phosphorus-based Lewis acids is reported. Corrole-based phosphorus(v) cations of the type [ArP(cor)][B(C(6)F(5))(4)] (Ar = C(6)H(5), 3,5-(CF(3))(2)C(6)H(3); cor = 5,10,15-(C(6)H(5))(3)corrolato(3–), 5,10,15-(C(6)F(5))(3)cor...

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Detalles Bibliográficos
Autores principales: Gilhula, James C., Radosevich, Alexander T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685354/
https://www.ncbi.nlm.nih.gov/pubmed/31588285
http://dx.doi.org/10.1039/c9sc02463h