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Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids
The synthesis and catalytic reactivity of a class of water-tolerant cationic phosphorus-based Lewis acids is reported. Corrole-based phosphorus(v) cations of the type [ArP(cor)][B(C(6)F(5))(4)] (Ar = C(6)H(5), 3,5-(CF(3))(2)C(6)H(3); cor = 5,10,15-(C(6)H(5))(3)corrolato(3–), 5,10,15-(C(6)F(5))(3)cor...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685354/ https://www.ncbi.nlm.nih.gov/pubmed/31588285 http://dx.doi.org/10.1039/c9sc02463h |