Cargando…
Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters
The synthesis of unsymmetrical axle [2]rotaxanes through a recently developed Ni-catalyzed C(sp(3))–C(sp(3)) cross-coupling of redox-active esters (formed directly from carboxylic acids) and organozinc reagents (derived from alkyl bromides) is reported. The method also furnishes, as a minor product,...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6686731/ https://www.ncbi.nlm.nih.gov/pubmed/31588296 http://dx.doi.org/10.1039/c9sc02457c |