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Unexpected polymerization mechanism of dilignol in the lignin growing

Lignin is an essential component of higher plants, which is built by the enzymatic dehydrogenative polymerization of monolignols. First, monolignol is enzymatically oxidized to produce the phenoxy radical, which can form resonance hybrids. Two radical resonant hybrids are coupled with each other to...

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Detalles Bibliográficos
Autores principales: Matsushita, Yasuyuki, Oyabu, Yuto, Aoki, Dan, Fukushima, Kazuhiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6689591/
https://www.ncbi.nlm.nih.gov/pubmed/31417743
http://dx.doi.org/10.1098/rsos.190445