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Crystal structure of a low-spin poly[di-μ(3)-cyanido-di-μ(2)-cyanido-bis(μ(2)-2-ethylpyrazine)dicopper(I)iron(II)]
In the title metal–organic framework, [Fe(C(6)H(8)N(2))(2){Cu(CN)(2)}(2)](n), the low-spin Fe(II) ion lies at an inversion centre and displays an elongated octahedral [FeN(6)] coordination environment. The axial positions are occupied by two symmetry-related bridging 2-ethylpyrazine ligands, while...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690451/ https://www.ncbi.nlm.nih.gov/pubmed/31417793 http://dx.doi.org/10.1107/S2056989019009496 |