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Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
The isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C(4)H(11)N(2))[CsBr(2)]}(n), and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C(4)H(11)N(2))[RbBr(2)]}(n), contain singly-protonated piperazin-1-ium cations and unusual ABr(6) (A = Cs or Rb) trigonal prisms. The p...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690459/ https://www.ncbi.nlm.nih.gov/pubmed/31417801 http://dx.doi.org/10.1107/S2056989019010375 |