Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms

The isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C(4)H(11)N(2))[CsBr(2)]}(n), and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C(4)H(11)N(2))[RbBr(2)]}(n), contain singly-protonated piperazin-1-ium cations and unusual ABr(6) (A = Cs or Rb) trigonal prisms. The p...

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Detalles Bibliográficos
Autores principales: Rickaby, Kirstie A., Slawin, Alexandra M. Z., Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690459/
https://www.ncbi.nlm.nih.gov/pubmed/31417801
http://dx.doi.org/10.1107/S2056989019010375
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author Rickaby, Kirstie A.
Slawin, Alexandra M. Z.
Harrison, William T. A.
author_facet Rickaby, Kirstie A.
Slawin, Alexandra M. Z.
Harrison, William T. A.
author_sort Rickaby, Kirstie A.
collection PubMed
description The isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C(4)H(11)N(2))[CsBr(2)]}(n), and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C(4)H(11)N(2))[RbBr(2)]}(n), contain singly-protonated piperazin-1-ium cations and unusual ABr(6) (A = Cs or Rb) trigonal prisms. The prisms are linked into a distinctive ‘curtain wall’ arrangement propagating in the (010) plane by face and edge sharing. In each case, a network of N—H⋯N, N—H⋯Br and N—H⋯(Br,Br) hydrogen bonds consolidates the structure.
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spelling pubmed-66904592019-08-15 Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms Rickaby, Kirstie A. Slawin, Alexandra M. Z. Harrison, William T. A. Acta Crystallogr E Crystallogr Commun Research Communications The isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C(4)H(11)N(2))[CsBr(2)]}(n), and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C(4)H(11)N(2))[RbBr(2)]}(n), contain singly-protonated piperazin-1-ium cations and unusual ABr(6) (A = Cs or Rb) trigonal prisms. The prisms are linked into a distinctive ‘curtain wall’ arrangement propagating in the (010) plane by face and edge sharing. In each case, a network of N—H⋯N, N—H⋯Br and N—H⋯(Br,Br) hydrogen bonds consolidates the structure. International Union of Crystallography 2019-07-26 /pmc/articles/PMC6690459/ /pubmed/31417801 http://dx.doi.org/10.1107/S2056989019010375 Text en © Rickaby et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Rickaby, Kirstie A.
Slawin, Alexandra M. Z.
Harrison, William T. A.
Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title_full Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title_fullStr Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title_full_unstemmed Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title_short Syntheses and structures of piperazin-1-ium ABr(2) (A = Cs or Rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing ABr(6) trigonal prisms
title_sort syntheses and structures of piperazin-1-ium abr(2) (a = cs or rb): hybrid solids containing ‘curtain wall’ layers of face- and edge-sharing abr(6) trigonal prisms
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690459/
https://www.ncbi.nlm.nih.gov/pubmed/31417801
http://dx.doi.org/10.1107/S2056989019010375
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