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An unexpected rhenium(IV)–rhenium(VII) salt: [Co(NH(3))(6)](3)[Re(VII)O(4)][Re(IV)F(6)](4)·6H(2)O
The title hydrated salt, tris[hexaamminecobalt(III)] tetraoxidorhenate(VII) tetrakis[hexafluoridorhenate(IV)] hexahydrate, arose unexpectedly due to possible contamination of the K(2)ReF(6) starting material with KReO(4). It consists of octahedral [Co(NH(3))(6)](3+) cation (Co1 site symmetry...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690467/ https://www.ncbi.nlm.nih.gov/pubmed/31417784 http://dx.doi.org/10.1107/S2056989019009757 |