Mechanistic Insight Into the AuCN Catalyzed Annulation Reaction of Salicylaldehyde and Aryl Acetylene: Cyanide Ion Promoted Umpolung Hydroacylation/Intramolecular Oxa-Michael Addition Mechanism

The detailed mechanism of the AuCN-catalyzed annulation of salicylaldehyde (SA) and phenyl acetylene leading to isoflavanone-type complexes has been investigated via density functional theory (DFT) calculations. Reaction pathways and possible stationary points are obtained with the combined molecula...

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Detalles Bibliográficos
Autores principales: Yang, Manyi, Wang, Guoqiang, Zou, Jingxiang, Li, Shuhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6691126/
https://www.ncbi.nlm.nih.gov/pubmed/31448263
http://dx.doi.org/10.3389/fchem.2019.00557

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6691126/
https://www.ncbi.nlm.nih.gov/pubmed/31448263
http://dx.doi.org/10.3389/fchem.2019.00557

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