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Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

As a synthesis technique, halide metathesis (n RM + M'X(n) → R(n)M' + n MX) normally relies for its effectiveness on the favorable formation of a metal halide byproduct (MX), often aided by solubility equilibria in solution. Owing to the lack of significant thermodynamic driving forces, in...

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Detalles Bibliográficos
Autores principales: Koby, Ross F, Rightmire, Nicholas R, Schley, Nathan D, Hanusa, Timothy P, Brennessel, William W
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6693392/
https://www.ncbi.nlm.nih.gov/pubmed/31467607
http://dx.doi.org/10.3762/bjoc.15.181