Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade

We previously showed that the regio- and stereoselectivity in terpene-forming reactions are determined by the conformations of the carbocation intermediates, which reflect the initial conformation of the substrate, geranylfarnesyl diphosphate (GFPP). However, it remains unclear how the initial confo...

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Detalles Bibliográficos
Autores principales: Sato, Hajime, Mitsuhashi, Takaaki, Yamazaki, Mami, Abe, Ikuro, Uchiyama, Masanobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6693403/
https://www.ncbi.nlm.nih.gov/pubmed/31467610
http://dx.doi.org/10.3762/bjoc.15.184

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6693403/
https://www.ncbi.nlm.nih.gov/pubmed/31467610
http://dx.doi.org/10.3762/bjoc.15.184

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