1,2,3-Triazolium-Derived Mesoionic Carbene Ligands Bearing Chiral Sulfur-Based Moieties: Synthesis, Catalytic Properties, and Their Role in Chirality Transfer

1,2,3-Triazole-derived mesoionic carbenes (MICs) having a chiral sulfur functional group at the C5 position are easily available through a CuAAC between chiral alkynyl sulfoxides and different azides. The MICs form complexes with several metals (Au, Ag, Ir, Rh, and Ru) that are enantiomerically pure...

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Detalles Bibliográficos
Autores principales: Sierra, Miguel A., de la Torre, María C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6705200/
https://www.ncbi.nlm.nih.gov/pubmed/31460425
http://dx.doi.org/10.1021/acsomega.9b01285

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6705200/
https://www.ncbi.nlm.nih.gov/pubmed/31460425
http://dx.doi.org/10.1021/acsomega.9b01285

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