Extraordinarily large kinetic isotope effect on alkene hydrogenation over Rh-based intermetallic compounds

A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H(2) and D(2) were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied. In styrene hydrogenation, the KIE values differed s...

Descripción completa

Detalles Bibliográficos
Autores principales: Furukawa, Shinya, Yi, Pingping, Kunisada, Yuji, Shimizu, Ken-Ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2019
Materias:
Focus on Intermetallic Catalysts
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6711132/
https://www.ncbi.nlm.nih.gov/pubmed/31489053
http://dx.doi.org/10.1080/14686996.2019.1642139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6711132/
https://www.ncbi.nlm.nih.gov/pubmed/31489053
http://dx.doi.org/10.1080/14686996.2019.1642139

Ejemplares similares