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Extraordinarily large kinetic isotope effect on alkene hydrogenation over Rh-based intermetallic compounds
A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H(2) and D(2) were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied. In styrene hydrogenation, the KIE values differed s...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Taylor & Francis
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6711132/ https://www.ncbi.nlm.nih.gov/pubmed/31489053 http://dx.doi.org/10.1080/14686996.2019.1642139 |