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Mechanistic Complexity of Asymmetric Transfer Hydrogenation with Simple Mn–Diamine Catalysts

[Image: see text] The catalytic asymmetric transfer hydrogenation (ATH) of ketones is a powerful methodology for the practical and efficient installation of chiral centers. Herein, we describe the synthesis, characterization, and catalytic application of a series of manganese complexes bearing simpl...

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Detalles Bibliográficos
Autores principales: van Putten, Robbert, Filonenko, Georgy A., Gonzalez de Castro, Angela, Liu, Chong, Weber, Manuela, Müller, Christian, Lefort, Laurent, Pidko, Evgeny
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713403/
https://www.ncbi.nlm.nih.gov/pubmed/31474784
http://dx.doi.org/10.1021/acs.organomet.9b00457