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Effector responsive hydroformylation catalysis

Herein, we report a supramolecular rhodium complex that can form dimeric or monomeric Rh-species catalytically active in hydroformylation, depending on the binding of effectors within the integrated DIM-receptor. X-ray crystal structures, in situ (high-pressure (HP)) spectroscopy studies, and molecu...

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Detalles Bibliográficos
Autores principales: Bai, Shao-Tao, Sinha, Vivek, Kluwer, Alexander M., Linnebank, Pim R., Abiri, Zohar, Dydio, Paweł, Lutz, Martin, de Bruin, Bas, Reek, Joost N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713872/
https://www.ncbi.nlm.nih.gov/pubmed/31489161
http://dx.doi.org/10.1039/c9sc02558h