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Why the Reactive Oxygen Species of the Fenton Reaction Switches from Oxoiron(IV) Species to Hydroxyl Radical in Phosphate Buffer Solutions? A Computational Rationale
[Image: see text] It has been shown that the major reactive oxygen species (ROS) generated by the aqueous reaction of Fe(II) and H(2)O(2) (i.e., the Fenton reaction) are high-valent oxoiron(IV) species, whereas the hydroxyl radical plays a role only in very acidic conditions. Nevertheless, when the...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6714542/ https://www.ncbi.nlm.nih.gov/pubmed/31497730 http://dx.doi.org/10.1021/acsomega.9b02023 |