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Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction

[Image: see text] The stability and formation of a perovskite structure is dictated by the Goldschmidt tolerance factor as a general geometric guideline. The tolerance factor has limited the choice of cations (A) in 3D lead iodide perovskites (APbI(3)), an intriguing class of semiconductors for high...

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Detalles Bibliográficos
Autores principales: Fu, Yongping, Hautzinger, Matthew P., Luo, Ziyu, Wang, Feifan, Pan, Dongxu, Aristov, Michael M., Guzei, Ilia A., Pan, Anlian, Zhu, Xiaoyang, Jin, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6716133/
https://www.ncbi.nlm.nih.gov/pubmed/31482120
http://dx.doi.org/10.1021/acscentsci.9b00367