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Unraveling the Arrangement of Al and Fe within the Framework Explains the Magnetism of Mixed-Metal MIL-100(Al,Fe)

[Image: see text] Properties of mixed-metal MOFs depend on the distribution of different metals within their frameworks. Determination of this distribution is often very challenging. Using an example of aluminum- and iron-containing MIL-100, we demonstrate that (27)Al NMR spectroscopy, when combined...

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Detalles Bibliográficos
Autores principales: Mali, Gregor, Mazaj, Matjaž, Arčon, Iztok, Hanžel, Darko, Arčon, Denis, Jagličić, Zvonko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6727378/
https://www.ncbi.nlm.nih.gov/pubmed/30869525
http://dx.doi.org/10.1021/acs.jpclett.9b00341