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Characterization of a trans–trans Carbonic Acid–Fluoride Complex by Infrared Action Spectroscopy in Helium Nanodroplets

[Image: see text] The high Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules. Herein, we report that carbonic acid, a thermodynamically disfavored species that is challenging to investigate exp...

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Detalles Bibliográficos
Autores principales: Thomas, Daniel A., Mucha, Eike, Lettow, Maike, Meijer, Gerard, Rossi, Mariana, von Helden, Gert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6727381/
https://www.ncbi.nlm.nih.gov/pubmed/30883095
http://dx.doi.org/10.1021/jacs.8b13542