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Characterization of a trans–trans Carbonic Acid–Fluoride Complex by Infrared Action Spectroscopy in Helium Nanodroplets
[Image: see text] The high Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules. Herein, we report that carbonic acid, a thermodynamically disfavored species that is challenging to investigate exp...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6727381/ https://www.ncbi.nlm.nih.gov/pubmed/30883095 http://dx.doi.org/10.1021/jacs.8b13542 |