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Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene

[Image: see text] We present to date the most efficient gram-scale synthesis of triangulene-4,8-dione and 12-hydroxytriangulene-4,8-dione, the precursors of Clar’s hydrocarbon, in overall yields >50%. The direct dihydroprecursors of triangulene, obtained upon reduction of triangulene-4,8-dione, w...

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Detalles Bibliográficos
Autores principales: Ribar, Peter, Šolomek, Tomáš, Juríček, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6737831/
https://www.ncbi.nlm.nih.gov/pubmed/31414815
http://dx.doi.org/10.1021/acs.orglett.9b02683