Sodium Diisopropylamide-Mediated Dehydrohalogenations: Influence of Primary- and Secondary-Shell Solvation

[Image: see text] Eliminations of alkyl halides by sodium diisopropylamide (NaDA) in tetrahydrofuran (THF)/hexane or THF/N,N-dimethylethylamine (DMEA) solutions are facile and complementary to analogous reactions of lithium diisopropylamide in THF. Rate studies show a dominance of monomer-based meta...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Yun, Algera, Russell F., Woltornist, Ryan A., Collum, David B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6737842/
https://www.ncbi.nlm.nih.gov/pubmed/31436099
http://dx.doi.org/10.1021/acs.joc.9b01428

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6737842/
https://www.ncbi.nlm.nih.gov/pubmed/31436099
http://dx.doi.org/10.1021/acs.joc.9b01428

Ejemplares similares