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Sodium Diisopropylamide-Mediated Dehydrohalogenations: Influence of Primary- and Secondary-Shell Solvation

[Image: see text] Eliminations of alkyl halides by sodium diisopropylamide (NaDA) in tetrahydrofuran (THF)/hexane or THF/N,N-dimethylethylamine (DMEA) solutions are facile and complementary to analogous reactions of lithium diisopropylamide in THF. Rate studies show a dominance of monomer-based meta...

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Detalles Bibliográficos
Autores principales:	Ma, Yun, Algera, Russell F., Woltornist, Ryan A., Collum, David B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6737842/ https://www.ncbi.nlm.nih.gov/pubmed/31436099 http://dx.doi.org/10.1021/acs.joc.9b01428

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