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Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
Although the chemistry of uranium-ligand multiple bonding is burgeoning, analogous complexes involving other actinides such as thorium remain rare and there are not yet any terminal thorium nitrides outside of cryogenic matrix isolation conditions. Here, we report evidence that reduction of a thoriu...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6744569/ https://www.ncbi.nlm.nih.gov/pubmed/31519900 http://dx.doi.org/10.1038/s41467-019-12206-5 |