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A Synthetic Model of Enzymatic [Fe(4)S(4)]–Alkyl Intermediates
[Image: see text] Although alkyl complexes of [Fe(4)S(4)] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this chal...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6748666/ https://www.ncbi.nlm.nih.gov/pubmed/31373801 http://dx.doi.org/10.1021/jacs.9b06975 |