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(−)- and (+)-Securidanes A and B, Natural Triarylmethane Enantiomers: Structure and Bioinspired Total Synthesis

Two pairs of enantiomers, (−) and (+)-securidanes A (1 and 2) and B (3 and 4) featuring unprecedented triarylmethane (TAM) skeletons, were isolated from Securidaca inappendiculata. Their structures were established by spectroscopic data, X-ray crystallography, and CD analysis. A plausible biosynthet...

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Detalles Bibliográficos
Autores principales: Zhou, B., Liu, D. X., Yuan, X. J., Li, J. Y., Xu, Y. C., Li, J., Li, Y., Yue, J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6750104/
https://www.ncbi.nlm.nih.gov/pubmed/31549026
http://dx.doi.org/10.1155/2018/2674182