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A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C–H Bond Activation

[Image: see text] Iron terminal imido species are typically implicated as reaction intermediates in iron-catalyzed transformations. While a large body of work has been devoted to mid- and high-valent iron imidos, to date the chemistry of iron(II) imidos has remained largely unexplored due to the dif...

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Detalles Bibliográficos
Autores principales: Cheng, Jun, Liu, Jian, Leng, Xuebing, Lohmiller, Thomas, Schnegg, Alexander, Bill, Eckhard, Ye, Shengfa, Deng, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6750749/
https://www.ncbi.nlm.nih.gov/pubmed/31083985
http://dx.doi.org/10.1021/acs.inorgchem.9b01147