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Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents

[Image: see text] α-Functionalization of alkyl boronic esters and homologation of aryl boronic esters by regioselective radical C(sp(3))–H activation in boron-ate complexes is reported. Reaction of commercial or readily accessed aryl boronic acid pinacol esters with alkyl lithium reagents provides b...

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Detalles Bibliográficos
Autores principales: Wang, Dinghai, Mück-Lichtenfeld, Christian, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6756585/
https://www.ncbi.nlm.nih.gov/pubmed/31454481
http://dx.doi.org/10.1021/jacs.9b07960