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Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions
Via regioselective Ir-catalyzed C–H borylation and subsequent reactions (i.e., viaBr(4)-Per or (BF(3)K)(4)-Per intermediates), we have introduced strong π-donors and acceptors at the 2,5,8,11-positions of perylene leading to unusual properties. Thus, incorporation of four donor diphenylamine (DPA) o...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6761871/ https://www.ncbi.nlm.nih.gov/pubmed/31588303 http://dx.doi.org/10.1039/c9sc02420d |