Electrochemical C–H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source

High-valent iron-oxo complexes are key intermediates in C–H functionalization reactions. Herein, we report the generation of a (TAML)Fe-oxo species (TAML = tetraamido macrocyclic ligand) via electrochemical proton-coupled oxidation of the corresponding (TAML)Fe(III)–OH(2) complex. Cyclic voltammetry...

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Detalles Bibliográficos
Autores principales: Das, Amit, Nutting, Jordan E., Stahl, Shannon S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6761876/
https://www.ncbi.nlm.nih.gov/pubmed/31588305
http://dx.doi.org/10.1039/c9sc02609f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6761876/
https://www.ncbi.nlm.nih.gov/pubmed/31588305
http://dx.doi.org/10.1039/c9sc02609f

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