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The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis

The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric t...

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Detalles Bibliográficos
Autores principales: Pichon, Delphine, Soleilhavoup, Michele, Morvan, Jennifer, Junor, Glen P., Vives, Thomas, Crévisy, Christophe, Lavallo, Vincent, Campagne, Jean-Marc, Mauduit, Marc, Jazzar, Rodolphe, Bertrand, Guy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6761915/
https://www.ncbi.nlm.nih.gov/pubmed/31588330
http://dx.doi.org/10.1039/c9sc02810b