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σ‐Noninnocence: Masked Phenyl‐Cation Transfer at Formal Ni(IV)
Reductive elimination is an elementary organometallic reaction step involving a formal oxidation state change of −2 at a transition‐metal center. For a series of formal high‐valent Ni(IV) complexes, aryl–CF(3) bond‐forming reductive elimination was reported to occur readily (Bour et al. J. Am. Chem....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771483/ https://www.ncbi.nlm.nih.gov/pubmed/31206937 http://dx.doi.org/10.1002/anie.201906658 |