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σ‐Noninnocence: Masked Phenyl‐Cation Transfer at Formal Ni(IV)

Reductive elimination is an elementary organometallic reaction step involving a formal oxidation state change of −2 at a transition‐metal center. For a series of formal high‐valent Ni(IV) complexes, aryl–CF(3) bond‐forming reductive elimination was reported to occur readily (Bour et al. J. Am. Chem....

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Detalles Bibliográficos
Autores principales: Steen, Jelte S., Knizia, Gerald, Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771483/
https://www.ncbi.nlm.nih.gov/pubmed/31206937
http://dx.doi.org/10.1002/anie.201906658