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Glycidyl Tosylate: Polymerization of a “Non‐Polymerizable” Monomer permits Universal Post‐Functionalization of Polyethers

Glycidyl tosylate appears to be a non‐polymerizable epoxide when nucleophilic initiators are used because of the excellent leaving group properties of the tosylate. However, using the monomer‐activated mechanism, this unusual monomer can be copolymerized with ethylene oxide (EO) and propylene oxide...

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Detalles Bibliográficos
Autores principales: Jung, Philipp, Ziegler, Arthur D., Blankenburg, Jan, Frey, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771516/
https://www.ncbi.nlm.nih.gov/pubmed/31339633
http://dx.doi.org/10.1002/anie.201904203