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Reactivity of Nickel(II) Porphyrins in oCVD Processes—Polymerisation, Intramolecular Cyclisation and Chlorination

Oxidative chemical vapour deposition of (5,15‐diphenylporphyrinato)nickel(II) (NiDPP) with iron(III) chloride as oxidant yielded a conjugated poly(metalloporphyrin) as a highly coloured thin film, which is potentially useful for optoelectronic applications. This study clarified the reactive sites of...

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Detalles Bibliográficos
Autores principales: Bengasi, Giuseppe, Baba, Kamal, Back, Oliver, Frache, Gilles, Heinze, Katja, Boscher, Nicolas D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771558/
https://www.ncbi.nlm.nih.gov/pubmed/30939219
http://dx.doi.org/10.1002/chem.201900793