Cavity Catalysis by Cooperative Vibrational Strong Coupling of Reactant and Solvent Molecules

Here, we report the catalytic effect of vibrational strong coupling (VSC) on the solvolysis of para‐nitrophenyl acetate (PNPA), which increases the reaction rate by an order of magnitude. This is observed when the microfluidic Fabry–Perot cavity in which the VSC is generated is tuned to the C=O vibr...

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Detalles Bibliográficos
Autores principales: Lather, Jyoti, Bhatt, Pooja, Thomas, Anoop, Ebbesen, Thomas W., George, Jino
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771697/
https://www.ncbi.nlm.nih.gov/pubmed/31189028
http://dx.doi.org/10.1002/anie.201905407

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771697/
https://www.ncbi.nlm.nih.gov/pubmed/31189028
http://dx.doi.org/10.1002/anie.201905407

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