Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd(I) Catalysis

S‐aryl phosphorothioates are privileged motifs in pharmaceuticals, agrochemicals, and catalysts; yet, the challenge of devising a straightforward synthetic route to enantioenriched S‐aryl phosphorothioates has remained unsolved to date. We demonstrate herein the first direct C−SP(=O)(OR′)(OR′′) coup...

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Detalles Bibliográficos
Autores principales: Chen, Xiang‐Yu, Pu, Maoping, Cheng, Hong‐Gang, Sperger, Theresa, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771726/
https://www.ncbi.nlm.nih.gov/pubmed/31190467
http://dx.doi.org/10.1002/anie.201906063

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771726/
https://www.ncbi.nlm.nih.gov/pubmed/31190467
http://dx.doi.org/10.1002/anie.201906063

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