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Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd(I) Catalysis
S‐aryl phosphorothioates are privileged motifs in pharmaceuticals, agrochemicals, and catalysts; yet, the challenge of devising a straightforward synthetic route to enantioenriched S‐aryl phosphorothioates has remained unsolved to date. We demonstrate herein the first direct C−SP(=O)(OR′)(OR′′) coup...
Autores principales: | Chen, Xiang‐Yu, Pu, Maoping, Cheng, Hong‐Gang, Sperger, Theresa, Schoenebeck, Franziska |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771726/ https://www.ncbi.nlm.nih.gov/pubmed/31190467 http://dx.doi.org/10.1002/anie.201906063 |
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