Covalency‐Driven Preservation of Local Charge Densities in a Metal‐to‐Ligand Charge‐Transfer Excited Iron Photosensitizer

Covalency is found to even out charge separation after photo‐oxidation of the metal center in the metal‐to‐ligand charge‐transfer state of an iron photosensitizer. The σ‐donation ability of the ligands compensates for the loss of iron 3d electronic charge, thereby upholding the initial metal charge...

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Detalles Bibliográficos
Autores principales: Jay, Raphael M., Eckert, Sebastian, Vaz da Cruz, Vinícius, Fondell, Mattis, Mitzner, Rolf, Föhlisch, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771958/
https://www.ncbi.nlm.nih.gov/pubmed/31145507
http://dx.doi.org/10.1002/anie.201904761

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771958/
https://www.ncbi.nlm.nih.gov/pubmed/31145507
http://dx.doi.org/10.1002/anie.201904761

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