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Covalency‐Driven Preservation of Local Charge Densities in a Metal‐to‐Ligand Charge‐Transfer Excited Iron Photosensitizer
Covalency is found to even out charge separation after photo‐oxidation of the metal center in the metal‐to‐ligand charge‐transfer state of an iron photosensitizer. The σ‐donation ability of the ligands compensates for the loss of iron 3d electronic charge, thereby upholding the initial metal charge...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771958/ https://www.ncbi.nlm.nih.gov/pubmed/31145507 http://dx.doi.org/10.1002/anie.201904761 |