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The Hydrogenobyric Acid Structure Reveals the Corrin Ligand as an Entatic State Module Empowering B(12) Cofactors for Catalysis

The B(12) cofactors instill a natural curiosity regarding the primordial selection and evolution of their corrin ligand. Surprisingly, this important natural macrocycle has evaded molecular scrutiny, and its specific role in predisposing the incarcerated cobalt ion for organometallic catalysis has r...

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Detalles Bibliográficos
Autores principales: Kieninger, Christoph, Deery, Evelyne, Lawrence, Andrew D., Podewitz, Maren, Wurst, Klaus, Nemoto‐Smith, Emi, Widner, Florian J., Baker, Joseph A., Jockusch, Steffen, Kreutz, Christoph R., Liedl, Klaus R., Gruber, Karl, Warren, Martin J., Kräutler, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771967/
https://www.ncbi.nlm.nih.gov/pubmed/31115943
http://dx.doi.org/10.1002/anie.201904713