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The Hydrogenobyric Acid Structure Reveals the Corrin Ligand as an Entatic State Module Empowering B(12) Cofactors for Catalysis
The B(12) cofactors instill a natural curiosity regarding the primordial selection and evolution of their corrin ligand. Surprisingly, this important natural macrocycle has evaded molecular scrutiny, and its specific role in predisposing the incarcerated cobalt ion for organometallic catalysis has r...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771967/ https://www.ncbi.nlm.nih.gov/pubmed/31115943 http://dx.doi.org/10.1002/anie.201904713 |