Octacarbonyl Ion Complexes of Actinides [An(CO)(8)](+/−) (An=Th, U) and the Role of f Orbitals in Metal–Ligand Bonding

The octacarbonyl cation and anion complexes of actinide metals [An(CO)(8)](+/−) (An=Th, U) are prepared in the gas phase and are studied by mass‐selected infrared photodissociation spectroscopy. Both the octacarbonyl cations and anions have been characterized to be saturated coordinated complexes. Q...

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Detalles Bibliográficos
Autores principales: Chi, Chaoxian, Pan, Sudip, Jin, Jiaye, Meng, Luyan, Luo, Mingbiao, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6772027/
https://www.ncbi.nlm.nih.gov/pubmed/31276242
http://dx.doi.org/10.1002/chem.201902625

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6772027/
https://www.ncbi.nlm.nih.gov/pubmed/31276242
http://dx.doi.org/10.1002/chem.201902625

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