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O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes
Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6772150/ https://www.ncbi.nlm.nih.gov/pubmed/31271694 http://dx.doi.org/10.1002/anie.201903902 |