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O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes

Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...

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Detalles Bibliográficos
Autores principales: Kroll, Nicole, Speckmann, Ina, Schoknecht, Marc, Gülzow, Jana, Diekmann, Marek, Pfrommer, Johannes, Stritt, Anika, Schlangen, Maria, Grohmann, Andreas, Hörner, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6772150/
https://www.ncbi.nlm.nih.gov/pubmed/31271694
http://dx.doi.org/10.1002/anie.201903902